Chemistry

Percent Ionic Character Calculator

Estimate ionic character from electronegativity difference.

Parameters Live Compute
Calculated Output
Percent ionic character (%) 71.155
ΔEN 2.23
Formula: % ionic = (1 − e^(−0.25·ΔEN²)) × 100
Step-by-Step Breakdown
1. Values used:
2. Electronegativity 1 = 3.16
3. Electronegativity 2 = 0.93
4.
5. Percent ionic character = 71.155%
6. ΔEN = Electronegativity 1 - Electronegativity 2 = 3.16 - 0.93 = 2.23
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Pauling's relation estimates how ionic a bond is from the electronegativity gap.

The math behind it

% ionic character = (1 − e^(−0.25 × ΔEN²)) × 100. Above ~50% the bond is considered ionic.

Worked Example

NaCl (ΔEN 2.23) → ~71% ionic.

Frequently Asked Questions

100%?

No real bond is fully ionic; even NaCl has some covalent character.

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